Chemical Reactivity of Würster’s Salts at Very High Pressure

CHEMICAL REACTION AT HIGH TEMPERATURE AND HIGH PRESSURE VI Polymorphic Transition in ZnP, at High Temperature and High Pressure

:1 new pressure-induced modification of zincdiphosphide, ZnP2, has been prepared by the di reel union o(zinc with phosphorus and also through the polymorphic transitions of both monoclinic and tetragonal ZnP2. The application of pressures above 20 kb combined with temperatures above 150'C is required for [be synthesis. The new modification of ZnP2 has a pseuda•cuhic cps[al symmetry with a latti...

Chemical diffusion of fluorine in jadeite melt at high pressure

The chemical diffusion of fluorine in jadeite melt has been investigated from 10 to 15 kbars and 1200 to 14OO“C using diffusion couples of jadeite melt and fluorine-bearing jadeite melt (6.3 wt.% F). The diffusion profile data indicate that the diffusion process is concentration-independent, binarv. F-O interdiffision. The F-O interdiffusion coefficient ranges from 1.3 X IO-’ to 7.1 X lo-’ cm*/...

High Temperature Oxidation Behaviour of Nimonic - 115 Alloy in Presence of Sodium Salts at 850OC

The high temperature oxidation behaviour of Nimonic-115 industrial alloy has been investigated in presence of  NaNO3, Na2CO3 and Na2O2 at 850oC in flowing air. The oxidation kinetics and effect of salt deposition for the period of 48 h were studied. The scale morphologies were determined on the basis of X-ray diffraction anal...

Low Pressure Chemical Vapour Deposition at Quasi- High Flow

A new chemical vapour deposition (CVD) technique is presented. It is especially advantageous for the deposition of compound materials. The technique improves the uniformity and reproducibility of the deposition. The economical use of gaseous reactants is improved by a factor varying between 5 and 20. This is important in the case of expensive metal-organic CVD methods. The method consists in th...

High Pressure Cw Chemical Laser